Advances in Difference Equations
Volume 2005 (2005), Issue 3, Pages 275-318
doi:10.1155/ADE.2005.275
Thermodynamic modeling, energy equipartition, and nonconservation
of entropy for discrete-time dynamical systems
1School of Aerospace Engineering, Georgia Institute of Technology, Atlanta 30332-0150, GA, USA
2Department of Mechanical, Aerospace and Biomedical Engineering, The University of Tennessee, Knoxville 37996-2210, TN, USA
Received 19 November 2004
Copyright © 2005 Wassim M. Haddad et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract
We develop thermodynamic models for discrete-time
large-scale dynamical systems. Specifically, using compartmental
dynamical system theory, we develop energy flow models possessing
energy conservation, energy equipartition, temperature
equipartition, and entropy nonconservation principles for
discrete-time, large-scale dynamical systems. Furthermore, we
introduce a new and dual notion to entropy; namely,
ectropy, as a measure of the tendency of a dynamical
system to do useful work and grow more organized, and show that
conservation of energy in an isolated thermodynamic system
necessarily leads to nonconservation of ectropy and entropy. In
addition, using the system ectropy as a Lyapunov function
candidate, we show that our discrete-time, large-scale
thermodynamic energy flow model has convergent trajectories to
Lyapunov stable equilibria determined by the system initial
subsystem energies.